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R-15

Group trends become explanations via Zeff, shielding and radius

Gets redefined

Confidence: verified

IB sub-topics affected

EditorialSub-topic tagging is this site’s own editorial judgement, not the IB’s.

The GCSE model

Group 1 gets more reactive down the group; group 7 gets less reactive down the group. Explanation: the outer electron is further from the nucleus / more shielded, so more easily lost.

The IB HL model

The same trends, but now derived from effective nuclear charge across a period (increasing Zeff with roughly constant shielding → smaller atoms, higher IE, higher electronegativity) and increasing n down a group. IB requires you to explain discontinuities: the dip from group 2 to group 13 (a p electron is higher in energy than an s electron in the same shell) and from group 15 to group 16 (electron pairing repulsion in a p orbital) — Structure 3.1.7. It also introduces the metallic → amphoteric → acidic oxide continuum across a period (3.1.5), and transition-metal specifics: variable oxidation states from close successive IEs (3.1.9), and colour from d-orbital splitting in complexes with the observed colour complementary to the absorbed colour (3.1.10).

What actually changes

From memorised trends to derived trends, with mandatory anomalies. And the reason for group-1 reactivity is now framed via ionisation energy, which requires R-04's subshell model.

Zeff and shielding require the subshell model.

Failure mode if not updated

Explaining trends by "more shells" alone without mentioning nuclear charge and shielding (loses marks); being unable to explain the IE discontinuities; assuming atomic radius increases across a period; saying a solution "is blue because it absorbs blue light".

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